|
|
Time-resolved x-ray diffraction as a tool
to investigate solid-solid
photoinduced transformations.
Eric Collet, France
Topics
-
X-ray diffraction is intensely used to solve crystal structures and makes it possible to better understand atomic interactions and the origin of physical properties. Time-resolved x-ray diffraction makes it possible to observe molecular reorganization as photoinduced transformation take place and gives information on the physical process. Very short x-ray pulses (ps or fs) makes it possible to observe phenomena at the time-scale of molecular or atomic motion with an atomic spatial resolution. During this lecture and after some reminder around x-ray diffraction, I will generally discuss the different informations we can probe with x-ray diffraction and especially around photoinduced phase transition, with example performed both with and without time-resolved experiments :
- relation between atomic motions and Bragg peak intensities.
- differences between local excitation and coherent processes.
- 3D ordering or disordering phenomena : symmetry breaking and signatures in diffraction.
- problem of coexistence of stable and photo-induced phases
- processes of the transformation and diffuse x-ray scattering : from the excited molecule to macroscopic transformation.
- An important part of the lecture will be devoted to some photo-active materials with the possibility of tuning their optical, magnetic, conduction or other physical properties by light stimuli.
|